Literature DB >> 26572219

Visible-Light-Driven Photocatalytic Initiation of Radical Thiol-Ene Reactions Using Bismuth Oxide.

Olugbeminiyi O Fadeyi1, James J Mousseau1, Yiqing Feng1, Christophe Allais1, Philippe Nuhant1, Ming Z Chen1, Betsy Pierce1, Ralph Robinson1.   

Abstract

A nontoxic and inexpensive photocatalytic initiation of anti-Markovnikov hydrothiolation of olefins using visible light is reported. This method is characterized by low catalyst loading, thereby enabling a mild and selective method for radical initiation in thiol-ene reactions between a wide scope of olefins and thiols.

Entities:  

Year:  2015        PMID： 26572219     DOI： 10.1021/acs.orglett.5b03184

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  7 in total

1.  Shedding light on the nature of the catalytically active species in photocatalytic reactions using Bi2O3 semiconductor.

Authors:  Paola Riente; Mauro Fianchini; Patricia Llanes; Miquel A Pericàs; Timothy Noël
Journal:  Nat Commun       Date:  2021-01-27       Impact factor: 14.919

Review 2.  All-carbon [3 + 2] cycloaddition in natural product synthesis.

Authors:  Zhuo Wang; Junyang Liu
Journal:  Beilstein J Org Chem       Date:  2020-12-09       Impact factor: 2.883

Review 3.  Recent Advances in Visible-Light Photoredox Catalysis for the Thiol-Ene/Yne Reactions.

Authors:  Qian Xiao; Qing-Xiao Tong; Jian-Ji Zhong
Journal:  Molecules       Date:  2022-01-18       Impact factor: 4.411

Review 4.  Photocatalytic formation of carbon-sulfur bonds.

Authors:  Alexander Wimmer; Burkhard König
Journal:  Beilstein J Org Chem       Date:  2018-01-05       Impact factor: 2.883

5.  Discovery and mechanistic study of a photocatalytic indoline dehydrogenation for the synthesis of elbasvir.

Authors:  Hatice G Yayla; Feng Peng; Ian K Mangion; Mark McLaughlin; Louis-Charles Campeau; Ian W Davies; Daniel A DiRocco; Robert R Knowles
Journal:  Chem Sci       Date:  2015-12-07       Impact factor: 9.825

Review 6.  Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis.

Authors:  Luca Capaldo; Davide Ravelli
Journal:  European J Org Chem       Date:  2017-03-02

Review 7.  Direct Photocatalyzed Hydrogen Atom Transfer (HAT) for Aliphatic C-H Bonds Elaboration.

Authors:  Luca Capaldo; Davide Ravelli; Maurizio Fagnoni
Journal:  Chem Rev       Date:  2021-08-06       Impact factor: 60.622
  7 in total

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