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Literature DB >> 26568268

Catalytic functionalization of low reactive C(sp(3))-H and C(sp(2))-H bonds of alkanes and arenes by carbene transfer from diazo compounds.

Ana Caballero¹, M Mar Díaz-Requejo, Manuel R Fructos, Andrea Olmos, Juan Urbano, Pedro J Pérez.

Abstract

The direct functionalization of low reactive C(sp(3))-H and C(sp(2))-H bonds of alkanes and arenes, respectively, by metal-induced carbene transfer from diazo compounds is reviewed. To date, this methodology has enabled the incorporation of CR(1)R(2) moieties from N2[double bond, length as m-dash]CR(1)R(2) in a chemo, regio, enantio or diastereoselective manner in those substrates with the appropriate selection of metal and ligands.

Entities: Chemical Species

Year: 2015 PMID： 26568268 DOI： 10.1039/c5dt03450g

Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390

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Cited

9 in total

1. Site-selective and stereoselective functionalization of non-activated tertiary C-H bonds.

Authors: Kuangbiao Liao; Thomas C Pickel; Vyacheslav Boyarskikh; John Bacsa; Djamaladdin G Musaev; Huw M L Davies
Journal: Nature Date: 2017-11-20 Impact factor: 49.962

2. Site-selective and stereoselective functionalization of unactivated C-H bonds.

Authors: Kuangbiao Liao; Solymar Negretti; Djamaladdin G Musaev; John Bacsa; Huw M L Davies
Journal: Nature Date: 2016-05-12 Impact factor: 49.962

3. "Sandwich" Diimine-Copper Catalysts for C-H Functionalization by Carbene Insertion.

Authors: Kristine Klimovica; Julius X Heidlas; Irvin Romero; Thanh V Le; Olafs Daugulis
Journal: Angew Chem Int Ed Engl Date: 2022-06-10 Impact factor: 16.823

4. Catalytic C(sp³)-H Alkylation via an Iron Carbene Intermediate.

Authors: Jennifer R Griffin; Chloe I Wendell; Jacob A Garwin; M Christina White
Journal: J Am Chem Soc Date: 2017-09-22 Impact factor: 15.419

5. Finding Opportunities from Surprises and Failures. Development of Rhodium-Stabilized Donor/Acceptor Carbenes and Their Application to Catalyst-Controlled C-H Functionalization.

Authors: Huw M L Davies
Journal: J Org Chem Date: 2019-10-10 Impact factor: 4.354

Catalytic functionalization of low reactive C(sp(3))-H and C(sp(2))-H bonds of alkanes and arenes by carbene transfer from diazo compounds.

1. Site-selective and stereoselective functionalization of non-activated tertiary C-H bonds.

2. Site-selective and stereoselective functionalization of unactivated C-H bonds.

3. "Sandwich" Diimine-Copper Catalysts for C-H Functionalization by Carbene Insertion.

4. Catalytic C(sp³)-H Alkylation via an Iron Carbene Intermediate.

5. Finding Opportunities from Surprises and Failures. Development of Rhodium-Stabilized Donor/Acceptor Carbenes and Their Application to Catalyst-Controlled C-H Functionalization.

Review 6. Challenges and opportunities for alkane functionalisation using molecular catalysts.

Review 7. Recent advances in C(sp(3))-H bond functionalization via metal-carbene insertions.

8. Iridium(iii)-bis(imidazolinyl)phenyl catalysts for enantioselective C-H functionalization with ethyl diazoacetate.

Review 9. Transition-Metal-Catalyzed Annulations Involving the Activation of C(sp³ )-H Bonds.

Catalytic functionalization of low reactive C(sp(3))-H and C(sp(2))-H bonds of alkanes and arenes by carbene transfer from diazo compounds.

1. Site-selective and stereoselective functionalization of non-activated tertiary C-H bonds.

2. Site-selective and stereoselective functionalization of unactivated C-H bonds.

3. "Sandwich" Diimine-Copper Catalysts for C-H Functionalization by Carbene Insertion.

4. Catalytic C(sp3)-H Alkylation via an Iron Carbene Intermediate.

5. Finding Opportunities from Surprises and Failures. Development of Rhodium-Stabilized Donor/Acceptor Carbenes and Their Application to Catalyst-Controlled C-H Functionalization.

Review 6. Challenges and opportunities for alkane functionalisation using molecular catalysts.

Review 7. Recent advances in C(sp(3))-H bond functionalization via metal-carbene insertions.

8. Iridium(iii)-bis(imidazolinyl)phenyl catalysts for enantioselective C-H functionalization with ethyl diazoacetate.

Review 9. Transition-Metal-Catalyzed Annulations Involving the Activation of C(sp3 )-H Bonds.

4. Catalytic C(sp³)-H Alkylation via an Iron Carbene Intermediate.

Review 9. Transition-Metal-Catalyzed Annulations Involving the Activation of C(sp³ )-H Bonds.