Literature DB >> 26565304

Ehrenfest approach to open double-well dynamics.

Stephen Choi1, Roberto Onofrio2,3, Bala Sundaram1.   

Abstract

We consider an Ehrenfest approximation for a particle in a double-well potential in the presence of an external environment schematized as a finite resource heat bath. This allows us to explore how the limitations in the applicability of Ehrenfest dynamics to nonlinear systems are modified in an open system setting. Within this framework, we have identified an environment-induced spontaneous symmetry breaking mechanism, and we argue that the Ehrenfest approximation becomes increasingly valid in the limit of strong coupling to the external reservoir, either in the form of an increasing number of oscillators or increasing temperature. The analysis also suggests a rather intuitive picture for the general phenomenon of quantum tunneling and its interplay with classical thermal activation processes, which may be of relevance in physical chemistry, ultracold atom physics, and fast-switching dynamics such as in superconducting digital electronics.

Year:  2015        PMID: 26565304     DOI: 10.1103/PhysRevE.92.042907

Source DB:  PubMed          Journal:  Phys Rev E Stat Nonlin Soft Matter Phys        ISSN: 1539-3755


  1 in total

1.  Coupled wave-packets for non-adiabatic molecular dynamics: a generalization of Gaussian wave-packet dynamics to multiple potential energy surfaces.

Authors:  Alexander White; Sergei Tretiak; Dmitry Mozyrsky
Journal:  Chem Sci       Date:  2016-04-25       Impact factor: 9.825

  1 in total

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