| Literature DB >> 26558744 |
Justin A Goodwin1, Carl F Ballesteros1, Aaron Aponick1.
Abstract
A complementary diastereoselective gold(I) or bismuth(III) catalyzed tandem hemiacetalization/dehydrative cyclization of 1,5-monoallylic diols was developed to access 1,3-dioxolanes and dioxanes. This methodology provides rapid access to protected 1,3-diols under mild conditions with high levels of diastereoselectivity.Entities:
Year: 2015 PMID： 26558744 DOI： 10.1021/acs.orglett.5b02725
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005