Literature DB >> 26554669

Observation of unusual slow-relaxation of the magnetisation in a Gd-EDTA chelate.

Rebecca J Holmberg1, Le Tuan Anh Ho, Liviu Ungur, Ilia Korobkov, Liviu F Chibotaru, Muralee Murugesu.   

Abstract

A Gadolinium EDTA chelate displays characteristic isotropic behaviour common of Gd(III) complexes under zero applied magnetic field, and anisotropic behaviour arising from dipolar coupling and weak spin-phonon coupling under an applied magnetic field. This surprising magnetic behaviour for Gd(III) is investigated using SQUID magnetometry and rationalized through theoretical calculations.

Entities:  

Year:  2015        PMID： 26554669     DOI： 10.1039/c5dt04072h

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  5 in total

1.  Magnetic Anisotropy Trends along a Full 4f-Series: The fn+7 Effect.

Authors:  Matteo Briganti; Eva Lucaccini; Laura Chelazzi; Samuele Ciattini; Lorenzo Sorace; Roberta Sessoli; Federico Totti; Mauro Perfetti
Journal:  J Am Chem Soc       Date:  2021-05-23       Impact factor: 15.419

2.  Giant exchange coupling and field-induced slow relaxation of magnetization in Gd2@C79N with a single-electron Gd-Gd bond.

Authors:  G Velkos; D S Krylov; K Kirkpatrick; X Liu; L Spree; A U B Wolter; B Büchner; H C Dorn; A A Popov
Journal:  Chem Commun (Camb)       Date:  2018-03-15       Impact factor: 6.222

3.  Molecular and Polymer Ln2M2 (Ln = Eu, Gd, Tb, Dy; M = Zn, Cd) Complexes with Pentafluorobenzoate Anions: The Role of Temperature and Stacking Effects in the Structure; Magnetic and Luminescent Properties.

Authors:  Maxim A Shmelev; Mikhail A Kiskin; Julia K Voronina; Konstantin A Babeshkin; Nikolay N Efimov; Evgenia A Varaksina; Vladislav M Korshunov; Ilya V Taydakov; Natalia V Gogoleva; Alexey A Sidorov; Igor L Eremenko
Journal:  Materials (Basel)       Date:  2020-12-13       Impact factor: 3.623

4.  Modulation of Slow Magnetic Relaxation in Gd(III)-Tetrahalosemiquinonate Complexes.

Authors:  Maja A Dunstan; Dominic S Brown; Lorenzo Sorace; Richard A Mole; Colette Boskovic
Journal:  Chem Asian J       Date:  2022-06-20

5.  Controlling Electron Spin Decoherence in Nd-based Complexes via Symmetry Selection.

Authors:  Jing Li; Lei Yin; Shi-Jie Xiong; Xing-Long Wu; Fei Yu; Zhong-Wen Ouyang; Zheng-Cai Xia; Yi-Quan Zhang; Johan van Tol; You Song; Zhenxing Wang
Journal:  iScience       Date:  2020-02-20
  5 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.