| Literature DB >> 26554575 |
Veeranna Yempally1, Wai Yip Fan2, Bruce A Arndtsen3, Ashfaq A Bengali1.
Abstract
Dissolution of M(CO)3(Br)(L(Ar)) [L(Ar) = (2,6-Cl2-C6H3-NCMe)2CH2] in either acetonitrile [M = Mn, Re] or benzonitrile (M = Re) results in C-C coupling of the nitrile to the diimine ligand. When reacted with acetonitrile, the intermediate adduct [M(CO)3(NCCH3)(L(Ar))]Br forms and undergoes an intramolecular C-C coupling reaction between the nitrile carbon and the methylene carbon of the β-diimine ligand.Entities:
Year: 2015 PMID： 26554575 DOI： 10.1021/acs.inorgchem.5b02087
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165