Literature DB >> 26545957

Potassium 4,5-Bis(dinitromethyl)furoxanate: A Green Primary Explosive with a Positive Oxygen Balance.

Chunlin He1, Jean'ne M Shreeve2.   

Abstract

Potassium 4,5-bis(dinitromethyl)furoxanate was synthesized readily from cyanoacetic acid. It was characterized by IR spectroscopy, elemental analysis, NMR spectroscopy, and differential scanning calorimetry (DSC), and the structure was confirmed by X-ray single-crystal diffraction. Its positive oxygen balance, high density (2.130 g cm(-3)), sensitivity (IS=2 J, FS=5 N), and calculated heat of formation (-421.0 kJ mol(-1)), combined with its calculated superior detonation performance (D=7759.0 m s(-1), P=27.3 GPa), make it a competitive replacement as a green primary explosive.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  energetic materials; furoxans; heterocycles; oxygen balance; primary explosives

Mesh：

Substances：

Year:  2015        PMID： 26545957     DOI： 10.1002/anie.201509209

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  8 in total

1.  Syntheses and Promising Properties of Dense Energetic 5,5'-Dinitramino-3,3'-azo-1,2,4-oxadiazole and Its Salts.

Authors:  Yongxing Tang; Haixiang Gao; Lauren A Mitchell; Damon A Parrish; Jean'ne M Shreeve
Journal:  Angew Chem Int Ed Engl       Date:  2016-01-28       Impact factor: 15.336

2.  A promising cation of 4-aminofurazan-3-carboxylic acid amidrazone in desensitizing energetic materials.

Authors:  Jichuan Zhang; Zhenyuan Wang; Yunhao Hsieh; Binshen Wang; Haifeng Huang; Jun Yang; Jiaheng Zhang
Journal:  RSC Adv       Date:  2020-01-14       Impact factor: 4.036

3.  New Strategy for Enhancing Energetic Properties by Regulating Trifuroxan Configuration: 3,4-Bis(3-nitrofuroxan-4-yl)furoxan.

Authors:  Lianjie Zhai; Fuqiang Bi; Yifen Luo; Naixing Wang; Junlin Zhang; Bozhou Wang
Journal:  Sci Rep       Date:  2019-03-13       Impact factor: 4.379

4.  A green metal-free fused-ring initiating substance.

Authors:  Mucong Deng; Yongan Feng; Wenquan Zhang; Xiujuan Qi; Qinghua Zhang
Journal:  Nat Commun       Date:  2019-03-22       Impact factor: 14.919

5.  Novel Energetic Coordination Polymers Based on 1,5-Di(nitramino)tetrazole With High Oxygen Content and Outstanding Properties: Syntheses, Crystal Structures, and Detonation Properties.

Authors:  Yanan Li; Tao Yu; Yiying Zhang; Jianjian Hu; Tao Chen; Yinglei Wang; Kangzhen Xu
Journal:  Front Chem       Date:  2019-10-15       Impact factor: 5.221

6.  A new oxygen-rich energetic salt dihydrazine tetranitroethide: a promising explosive alternative with high density and good performance.

Authors:  Haozheng Mei; Junqing Yang; Wenli Cao; Yong Hu; Piao He; Jian-Guo Zhang
Journal:  RSC Adv       Date:  2020-06-17       Impact factor: 4.036

7.  Preparation of a nanoscale homogeneous energetic lead azides@porous carbon hybrid with high ignition ability by in situ synthesis.

Authors:  Zhenzhan Yan; Li Yang; Ji-Min Han; Naimeng Song; Jianchao Liu
Journal:  RSC Adv       Date:  2020-04-08       Impact factor: 3.361

8.  An energetic composite formed of wrinkled rGO sheets wrapped around copper azide nanowires with higher electrostatic safety as a green primary explosive.

Authors:  Xuwen Liu; Yan Hu; Tingting Li; Yinghua Ye; Ruiqi Shen
Journal:  RSC Adv       Date:  2020-08-19       Impact factor: 4.036
  8 in total

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