Literature DB >> 26526489

An improved synthesis of [26-(2)H3]castasterone.

Vladimir N Zhabinskii1, Olga V Gulyakevich1, Peter V Kurman1, Polina S Shabunya1, Svetlana A Fatykhava1, Vladimir A Khripach1.   

Abstract

Commercially available epicastasterone has been employed as a starting material for the preparation of [26-(2)H3 ]castasterone. The chemical synthesis has been realized in 13 chemical steps and 4.6% total yield. The target compound is intended to be used as internal standard for the quantitative analysis of brassinosteroids.
Copyright © 2015 John Wiley & Sons, Ltd.

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Keywords:  brassinosteroids; castasterone; deuterium; epicastasterone; synthesis

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Year:  2015        PMID: 26526489     DOI: 10.1002/jlcr.3353

Source DB:  PubMed          Journal:  J Labelled Comp Radiopharm        ISSN: 0362-4803            Impact factor:   1.921


  1 in total

1.  Synthesis of ergostane-type brassinosteroids with modifications in ring A.

Authors:  Vladimir N Zhabinskii; Darya A Osiyuk; Yuri V Ermolovich; Natalia M Chaschina; Tatsiana S Dalidovich; Miroslav Strnad; Vladimir A Khripach
Journal:  Beilstein J Org Chem       Date:  2017-11-02       Impact factor: 2.883

  1 in total

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