| Literature DB >> 26523735 |
Taigang Zhou1, Fei-Xian Luo1, Ming-Yu Yang1, Zhang-Jie Shi1,2.
Abstract
Selective cleavage of an inert C-C bond followed by C-O/N bond formation through a long-distance aryl migration from a carbon to a nitrogen center via Ag catalysis is reported. The migration products were easily converted into γ-hydroxy amines and tetrahydroquinoline derivatives in quantitative yields. Preliminary mechanistic studies indicated a radical pathway.Entities:
Year: 2015 PMID： 26523735 DOI： 10.1021/jacs.5b10267
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419