Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Electronic vs. structural ordering in a manganese(III) spin crossover complex.

Literature DB >> 26501138

Electronic vs. structural ordering in a manganese(III) spin crossover complex.

Anthony J Fitzpatrick¹, Elzbieta Trzop, Eliza Trzop², Helge Müller-Bunz¹, Marinela M Dîrtu³, Yann Garcia³, Eric Collet², Grace G Morgan¹.

Abstract

A symmetry breaking spin transition in a Mn(III) complex is reported with three structural phases, a high symmetry high temperature S = 2 phase, an intermediate S = 1/S = 2 ordered phase and an aperiodic low temperature phase with S = 1 cations. The aperiodicity is interpreted as resulting from long-range ordering of the NTf2(-) anions.

Entities: Chemical Gene

Year: 2015 PMID： 26501138 DOI： 10.1039/c5cc05129k

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

Keyword Cloud
Cited

4 in total

1. Modulation of Mn³⁺ Spin State by Guest Molecule Inclusion.

Authors: Irina A Kühne; Kane Esien; Laurence C Gavin; Helge Müller-Bunz; Solveig Felton; Grace G Morgan
Journal: Molecules Date: 2020-11-28 Impact factor: 4.411

2. Domain Wall Dynamics in a Ferroelastic Spin Crossover Complex with Giant Magnetoelectric Coupling.

Authors: Vibe Boel Jakobsen; Elzbieta Trzop; Emiel Dobbelaar; Laurence C Gavin; Shalinee Chikara; Xiaxin Ding; Minseong Lee; Kane Esien; Helge Müller-Bunz; Solveig Felton; Eric Collet; Michael A Carpenter; Vivien S Zapf; Grace G Morgan
Journal: J Am Chem Soc Date: 2021-12-23 Impact factor: 15.419

3. Homochiral Mn³⁺ Spin-Crossover Complexes: A Structural and Spectroscopic Study.

Authors: Irina A Kühne; Andrew Ozarowski; Aizuddin Sultan; Kane Esien; Anthony B Carter; Paul Wix; Aoife Casey; Mooneerah Heerah-Booluck; Tony D Keene; Helge Müller-Bunz; Solveig Felton; Stephen Hill; Grace G Morgan
Journal: Inorg Chem Date: 2022-02-17 Impact factor: 5.165

4. Spin-Crossover and Slow Magnetic Relaxation Behavior in Hexachlororhenate(IV) Salts of Mn(III) Complexes [Mn(5-Hal-sal₂323)]₂[ReCl₆] (Hal = Cl, Br).

Authors: Aleksandra V Tiunova; Anna V Kazakova; Denis V Korchagin; Gennady V Shilov; Sergey M Aldoshin; Aleksei I Dmitriev; Mikhail V Zhidkov; Konstantin V Zakharov; Eduard B Yagubskii
Journal: Int J Mol Sci Date: 2022-09-28 Impact factor: 6.208

4 in total

Electronic vs. structural ordering in a manganese(III) spin crossover complex.

1. Modulation of Mn3+ Spin State by Guest Molecule Inclusion.

2. Domain Wall Dynamics in a Ferroelastic Spin Crossover Complex with Giant Magnetoelectric Coupling.

3. Homochiral Mn3+ Spin-Crossover Complexes: A Structural and Spectroscopic Study.

4. Spin-Crossover and Slow Magnetic Relaxation Behavior in Hexachlororhenate(IV) Salts of Mn(III) Complexes [Mn(5-Hal-sal2323)]2[ReCl6] (Hal = Cl, Br).

1. Modulation of Mn³⁺ Spin State by Guest Molecule Inclusion.

3. Homochiral Mn³⁺ Spin-Crossover Complexes: A Structural and Spectroscopic Study.

4. Spin-Crossover and Slow Magnetic Relaxation Behavior in Hexachlororhenate(IV) Salts of Mn(III) Complexes [Mn(5-Hal-sal₂323)]₂[ReCl₆] (Hal = Cl, Br).