Literature DB >> 26486562

Atom precise platinum-thiol crowns.

Anu George1, K S Asha, Arthur C Reber, Scott R Biltek, Anthony F Pedicini, Ayusman Sen, Shiv N Khanna, Sukhendu Mandal.   

Abstract

Ligand stabilized water soluble Pt nanoclusters were synthesized and characterized through electrospray ionization mass spectrometry. Glutathione was used as the ligand, and Pt5(SG)10, and Pt6(SG)12 clusters were synthesized. Theoretical investigations found that these clusters do not possess a metal core, but rather are most stable in a ring structure. The clusters are stabilized through the thiol ligands forming a square planar structure around each Pt atom to form a ring. The structural elucidation was confirmed through UV/Vis and IR spectroscopy.

Entities:  

Year:  2015        PMID: 26486562     DOI: 10.1039/c5nr05325k

Source DB:  PubMed          Journal:  Nanoscale        ISSN: 2040-3364            Impact factor:   7.790


  1 in total

1.  Platinum clusters with precise numbers of atoms for preparative-scale catalysis.

Authors:  Takane Imaoka; Yuki Akanuma; Naoki Haruta; Shogo Tsuchiya; Kentaro Ishihara; Takeshi Okayasu; Wang-Jae Chun; Masaki Takahashi; Kimihisa Yamamoto
Journal:  Nat Commun       Date:  2017-09-25       Impact factor: 14.919

  1 in total

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