Orientational ordering of confined hard rods: the effect of shape anisotropy on surface ordering and capillary nematization.

We examine the ordering properties of rectangular hard rods with length L and diameter D at a single planar wall and between two parallel hard walls using the second virial density-functional theory. The theory is implemented in the three-state Zwanzig approximation, where only three mutually perpendicular directions are allowed for the orientations of hard rods. The effect of varying shape anisotropy is examined at L/D=10,15,and20. In contact with a single hard wall, the density profiles show planar ordering, damped oscillatory behavior, and a wall-induced surface ordering transition below the coexisting isotropic density of a bulk isotropic-nematic (I-N) phase transition. Upon approaching the coexisting isotropic density, the thickness of the nematic film diverges logarithmically, i.e., the nematic wetting is complete for any shape anisotropy. In the case of confinement between two parallel hard walls, it is found that the continuous surface ordering transition depends strongly on the distance between confining walls H for H<L, while it depends weakly on H for H>L. The minimal density at which a surface ordering transition can be realized is located at around H∼2D for all studied shape anisotropies due to the strong interference effect between the two hard walls. The first-order I-N phase transition of the bulk system becomes a surface ordered isotropic I_{B} to capillary nematic N_{B} phase transition in the slit pore. This first-order I_{B}-N_{B} transition weakens with decreasing pore width and terminates in a critical point for all studied shape anisotropies.