Literature DB >> 26462592

Symmetry constraints on spin dynamics: Application to hyperpolarized NMR.

Malcolm H Levitt1.   

Abstract

Spin dynamical evolution is constrained by the symmetries of the spin Hamiltonians that generate the quantum dynamics. The consequences of symmetry-induced constraints are examined for some common hyperpolarized NMR experiments, including the excitation of singlet order in spin-pair systems, and the transfer of parahydrogen-induced hyperpolarized singlet order to magnetization in systems displaying chemical and magnetic equivalence.
Copyright © 2015 Elsevier Inc. All rights reserved.

Entities:  

Keywords:  Chemical equivalence; Long-lived states; Magnetic equivalence; Permutation symmetry; Spin dynamics; Unitary bounds

Year:  2015        PMID： 26462592     DOI： 10.1016/j.jmr.2015.08.021

Source DB:  PubMed          Journal:  J Magn Reson        ISSN： 1090-7807            Impact factor:   2.229


  12 in total

1.  Hyperpolarizing Concentrated Metronidazole 15 NO2 Group over Six Chemical Bonds with More than 15 % Polarization and a 20 Minute Lifetime.

Authors:  Roman V Shchepin; Jonathan R Birchall; Nikita V Chukanov; Kirill V Kovtunov; Igor V Koptyug; Thomas Theis; Warren S Warren; Juri G Gelovani; Boyd M Goodson; Sepideh Shokouhi; Matthew S Rosen; Yi-Fen Yen; Wellington Pham; Eduard Y Chekmenev
Journal:  Chemistry       Date:  2019-05-30       Impact factor: 5.236

2.  Relaxation Dynamics of Nuclear Long-Lived Spin States in Propane and Propane-d6 Hyperpolarized by Parahydrogen.

Authors:  Nuwandi M Ariyasingha; Oleg G Salnikov; Kirill V Kovtunov; Larisa M Kovtunova; Valerii I Bukhtiyarov; Boyd M Goodson; Matthew S Rosen; Igor V Koptyug; Juri G Gelovani; Eduard Y Chekmenev
Journal:  J Phys Chem C Nanomater Interfaces       Date:  2019-04-11       Impact factor: 4.126

3.  Over 20% (15)N Hyperpolarization in Under One Minute for Metronidazole, an Antibiotic and Hypoxia Probe.

Authors:  Danila A Barskiy; Roman V Shchepin; Aaron M Coffey; Thomas Theis; Warren S Warren; Boyd M Goodson; Eduard Y Chekmenev
Journal:  J Am Chem Soc       Date:  2016-06-23       Impact factor: 15.419

4.  A Hyperpolarizable 1 H Magnetic Resonance Probe for Signal Detection 15 Minutes after Spin Polarization Storage.

Authors:  Soumya S Roy; Philip Norcott; Peter J Rayner; Gary G R Green; Simon B Duckett
Journal:  Angew Chem Int Ed Engl       Date:  2016-11-15       Impact factor: 15.336

5.  NMR SLIC Sensing of Hydrogenation Reactions Using Parahydrogen in Low Magnetic Fields.

Authors:  Danila A Barskiy; Oleg G Salnikov; Roman V Shchepin; Matthew A Feldman; Aaron M Coffey; Kirill V Kovtunov; Igor V Koptyug; Eduard Y Chekmenev
Journal:  J Phys Chem C Nanomater Interfaces       Date:  2016-10-26       Impact factor: 4.126

6.  SpinDynamica: Symbolic and numerical magnetic resonance in a Mathematica environment.

Authors:  Christian Bengs; Malcolm H Levitt
Journal:  Magn Reson Chem       Date:  2017-09-20       Impact factor: 2.447

7.  Singlet-filtered NMR spectroscopy.

Authors:  Salvatore Mamone; Nasrollah Rezaei-Ghaleh; Felipe Opazo; Christian Griesinger; Stefan Glöggler
Journal:  Sci Adv       Date:  2020-02-21       Impact factor: 14.136

8.  Magnetization Lifetimes Prediction and Measurements Using Long-Lived Spin States in Endogenous Molecules.

Authors:  F Teleanu; C Tuță; A Cucoanes; S Vasilca; P R Vasos
Journal:  Molecules       Date:  2020-11-24       Impact factor: 4.411

9.  Rapid hyperpolarization and purification of the metabolite fumarate in aqueous solution.

Authors:  Stephan Knecht; John W Blanchard; Danila Barskiy; Eleonora Cavallari; Laurynas Dagys; Erik Van Dyke; Maksim Tsukanov; Bea Bliemel; Kerstin Münnemann; Silvio Aime; Francesca Reineri; Malcolm H Levitt; Gerd Buntkowsky; Alexander Pines; Peter Blümler; Dmitry Budker; James Eills
Journal:  Proc Natl Acad Sci U S A       Date:  2021-03-30       Impact factor: 11.205

10.  Generating and sustaining long-lived spin states in 15N,15N'-azobenzene.

Authors:  Kirill F Sheberstov; Hans-Martin Vieth; Herbert Zimmermann; Bogdan A Rodin; Konstantin L Ivanov; Alexey S Kiryutin; Alexandra V Yurkovskaya
Journal:  Sci Rep       Date:  2019-12-27       Impact factor: 4.379
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