| Literature DB >> 26457658 |
Janelle E Steves1, Shannon S Stahl1.
Abstract
Two solutions, one consisting of bpy/TEMPO/NMI and the other bpy/ABNO/NMI (bpy =2,2'-bipyridyl; TEMPO = 2,2,6,6-tetramethylpiperidine N-oxyl, ABNO = 9-azabicyclo[3.3.1]nonane N-oxyl; NMI = N-methylimidazole), in acetonitrile are shown to have good long-term stability (≥1 year) under air at 5 °C. The solutions may be combined in appropriate quantities with commercially available [Cu(MeCN)4]OTf to provide a convenient catalyst system for the aerobic oxidation of primary and secondary alcohols.Entities:
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Year: 2015 PMID： 26457658 DOI： 10.1021/acs.joc.5b01950
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354