Literature DB >> 26447366

A high-pressure crystallographic and magnetic study of Na5[Mn(l-tart)2]·12H2O (l-tart = l-tartrate).

Gavin A Craig1, Christopher H Woodall, Scott C McKellar, Michael R Probert, Konstantin V Kamenev, Stephen A Moggach, Euan K Brechin, Simon Parsons, Mark Murrie.   

Abstract

The crystal structure and magnetic properties of the compound Na5[Mn(l-tart)2]·12H2O (1, l-tart = l-tartrate) have been investigated over the pressure range 0.34-3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na(+) ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.

Entities:  

Year:  2015        PMID: 26447366     DOI: 10.1039/c5dt03320a

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  2 in total

1.  Probing the origin of the giant magnetic anisotropy in trigonal bipyramidal Ni(ii) under high pressure.

Authors:  Gavin A Craig; Arup Sarkar; Christopher H Woodall; Moya A Hay; Katie E R Marriott; Konstantin V Kamenev; Stephen A Moggach; Euan K Brechin; Simon Parsons; Gopalan Rajaraman; Mark Murrie
Journal:  Chem Sci       Date:  2017-12-19       Impact factor: 9.825

2.  Behavior of Occupied and Void Space in Molecular Crystal Structures at High Pressure.

Authors:  Cameron J G Wilson; Tomas Cervenka; Peter A Wood; Simon Parsons
Journal:  Cryst Growth Des       Date:  2022-03-22       Impact factor: 4.076

  2 in total

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