Literature DB >> 26434632

Self-selecting homochiral quadruple-stranded helicates and control of supramolecular chirality.

Stephanie A Boer1, David R Turner.   

Abstract

Enantiomeric M4L4 helical cages have been prepared whose supramolecular chirality is induced by the chemical chirality of the self-sorting amino acid-derived ligands that are used. Using scrambled diastereomeric ligands or achiral glycine-derived ligands yields analogous complexes yet 'turns off' the supramolecular chirality by producing centrosymmetric cages.

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Year:  2015        PMID： 26434632     DOI： 10.1039/c5cc07422c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Enzyme classification using complex dynamic hemithioacetal systems.

Authors:  Yan Zhang; H Surangi N Jayawardena; Mingdi Yan; Olof Ramström
Journal:  Chem Commun (Camb)       Date:  2016-03-18       Impact factor: 6.222

2.  Homochiral Self-Sorted and Emissive IrIII Metallo-Cryptophanes.

Authors:  Victoria E Pritchard; Diego Rota Martir; Samuel Oldknow; Shumpei Kai; Shuichi Hiraoka; Nikki J Cookson; Eli Zysman-Colman; Michaele J Hardie
Journal:  Chemistry       Date:  2017-04-20       Impact factor: 5.236

3.  Chiral Self-Discrimination and Guest Recognition in Helicene-Based Coordination Cages.

Authors:  Thorben R Schulte; Julian J Holstein; Guido H Clever
Journal:  Angew Chem Int Ed Engl       Date:  2019-03-21       Impact factor: 15.336

4.  Helix-mediated over 1 nm-range chirality recognition by ligand-to-ligand interactions of dinuclear helicates.

Authors:  Natsumi Suko; Hideki Itamoto; Yoshinori Okayasu; Naoya Okura; Junpei Yuasa
Journal:  Chem Sci       Date:  2021-05-19       Impact factor: 9.825
  4 in total

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