| Literature DB >> 26428989 |
Kotaro Hiramatsu1, Takashi Nagata2.
Abstract
We report the development of broadband and sensitive time-resolved circular dichroism (TRCD) spectroscopy by exploiting optical heterodyne detection. Using this method, transient CD signals of submillidegree level can be detected over the spectral range of 415-730 nm. We also demonstrate that the broadband measurement with the aid of singular value decomposition enables the discrimination of genuine TRCD signals from artificial optical-anisotropy, such as linear birefringence and linear dichroism, induced by photoexcitation.Entities:
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Year: 2015 PMID： 26428989 DOI： 10.1063/1.4932229
Source DB: PubMed Journal: J Chem Phys ISSN： 0021-9606 Impact factor: 3.488