Literature DB >> 26426571

anti-Selective aminofluorination of alkenes with amidines mediated by hypervalent iodine(iii) reagents.

Hui Chen1, Atsushi Kaga, Shunsuke Chiba.   

Abstract

anti-Selective aminofluorination of alkenes with amidines was enabled by hypervalent iodine(iii) reagents, affording 4-fluoroalkyl-2-imidazolines. Further reductive ring-opening of the 2-imidazoline moiety could deliver highly functionalized 3-fluoropropane-1,2-diamine derivatives.

Entities:  

Year:  2015        PMID： 26426571     DOI： 10.1039/c5ob01854d

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  3 in total

1.  Catalytic Diastereo- and Enantioselective Fluoroamination of Alkenes.

Authors:  Katrina M Mennie; Steven M Banik; Elaine C Reichert; Eric N Jacobsen
Journal:  J Am Chem Soc       Date:  2018-03-29       Impact factor: 15.419

2.  Regio- and Enantioselective Intermolecular Aminofluorination of Alkenes via Iodine(I)/Iodine(III) Catalysis.

Authors:  Michael Schäfer; Timo Stünkel; Constantin G Daniliuc; Ryan Gilmour
Journal:  Angew Chem Int Ed Engl       Date:  2022-06-28       Impact factor: 16.823

3.  Hypercoordinate iodine for catalytic asymmetric diamination of styrene: insights into the mechanism, role of solvent, and stereoinduction.

Authors:  A Sreenithya; Christopher M Hadad; Raghavan B Sunoj
Journal:  Chem Sci       Date:  2019-06-10       Impact factor: 9.825
  3 in total

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