| Literature DB >> 26421326 |
B A Albani1, B Peña2, S Saha2, J K White1, A M Schaeffer1, K R Dunbar2, C Turro1.
Abstract
{[Ru(CH3CN)3]2(tppz)}(4+) (tppz = tetra-2-pyridylpyrazine) undergoes photoinduced CH3CN exchange with λirr ≥ 610 nm in H2O. In contrast, cis-{[Ru(tpy)(L)]2(bpm)}(4+) (tpy = 2,2':6',2''-terpyridine, bpm = 2,2'-bipyrimidine, L = CH3CN) is not reactive, but the complex with L = DMSO is photoactive. These complexes are potentially useful for the release of multiply caged drugs.Entities:
Year: 2015 PMID： 26421326 DOI： 10.1039/c5cc04913j
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222