Literature DB >> 26418747

Manganese(I)-Catalyzed C-H Aminocarbonylation of Heteroarenes.

Weiping Liu1, Jonas Bang1, Yujiao Zhang1, Lutz Ackermann2.   

Abstract

A versatile manganese(I) catalyst was employed in C-H aminocarbonylation reactions of heteroarenes with aryl as well as with alkyl isocyanates using a removable directing group approach. Detailed experimental mechanistic studies were suggestive of an organometallic C-H manganesation step, followed by a rate-determining migratory insertion.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  C-H activation; indoles; isocyanates; manganese; reaction mechanisms

Year:  2015        PMID： 26418747     DOI： 10.1002/anie.201507087

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  8 in total

1.  Transition-Metal-Catalyzed C-H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds.

Authors:  Joshua R Hummel; Jeffrey A Boerth; Jonathan A Ellman
Journal:  Chem Rev       Date:  2016-12-12       Impact factor: 60.622

Review 2.  A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

Authors:  Carlo Sambiagio; David Schönbauer; Remi Blieck; Toan Dao-Huy; Gerit Pototschnig; Patricia Schaaf; Thomas Wiesinger; Muhammad Farooq Zia; Joanna Wencel-Delord; Tatiana Besset; Bert U W Maes; Michael Schnürch
Journal:  Chem Soc Rev       Date:  2018-08-28       Impact factor: 54.564

3.  Manganese dioxide nanosheets induce mitochondrial toxicity in fish gill epithelial cells.

Authors:  Cynthia L Browning; Allen Green; Evan P Gray; Robert Hurt; Agnes B Kane
Journal:  Nanotoxicology       Date:  2021-01-27       Impact factor: 5.913

4.  Manganese-catalyzed allylation via sequential C-H and C-C/C-Het bond activation.

Authors:  Qingquan Lu; Felix J R Klauck; Frank Glorius
Journal:  Chem Sci       Date:  2017-02-24       Impact factor: 9.825

5.  Tertiary amine-directed and involved carbonylative cyclizations through Pd/Cu-cocatalyzed multiple C-X (X = H or N) bond cleavage.

Authors:  Qiu-Chao Mu; Yi-Xue Nie; Xing-Feng Bai; Jing Chen; Lei Yang; Zheng Xu; Li Li; Chun-Gu Xia; Li-Wen Xu
Journal:  Chem Sci       Date:  2019-08-19       Impact factor: 9.825

6.  External oxidant-compatible phosphorus(III)-directed site-selective C-H carbonylation.

Authors:  Ben Dong; Jiasheng Qian; Mingjie Li; Zheng-Jun Wang; Minyan Wang; Dingyi Wang; Chengkai Yuan; Ying Han; Yue Zhao; Zhuangzhi Shi
Journal:  Sci Adv       Date:  2020-12-16       Impact factor: 14.136

7.  Manganese(I)-Catalyzed C-H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination.

Authors:  Nasiru P Yahaya; Kate M Appleby; Magdalene Teh; Conrad Wagner; Erik Troschke; Joshua T W Bray; Simon B Duckett; L Anders Hammarback; Jonathan S Ward; Jessica Milani; Natalie E Pridmore; Adrian C Whitwood; Jason M Lynam; Ian J S Fairlamb
Journal:  Angew Chem Int Ed Engl       Date:  2016-09-07       Impact factor: 15.336

8.  Aromatic C-H addition of ketones to imines enabled by manganese catalysis.

Authors:  Bingwei Zhou; Yuanyuan Hu; Ting Liu; Congyang Wang
Journal:  Nat Commun       Date:  2017-10-27       Impact factor: 14.919
  8 in total

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