| Literature DB >> 26415984 |
Bei Zhang1, Sameh Kaziz, Houhua Li, Dawid Wodka, Sami Malola, Olga Safonova, Maarten Nachtegaal, Clément Mazet, Igor Dolamic, Jordi Llorca, Elina Kalenius, Latévi Max Lawson Daku, Hannu Hakkinen, Thomas Bürgi, Noelia Barrabés.
Abstract
The location of the Pd atoms in Pd2Au36(SC2H4Ph)24, is studied both experimentally and theoretically. X-ray photoelectron spectroscopy (XPS) indicates oxidized Pd atoms. Palladium K-edge extended X-ray absorption fine-structure (EXAFS) data clearly show Pd-S bonds, which is supported by far infrared spectroscopy and by comparing theoretical EXAFS spectra in R space and circular dichroism spectra of the staple, surface and core doped structures with experimental spectra.Entities:
Year: 2015 PMID: 26415984 DOI: 10.1039/c5nr04324g
Source DB: PubMed Journal: Nanoscale ISSN: 2040-3364 Impact factor: 7.790