Literature DB >> 26414483

Bandgap Tunability in Sb-Alloyed BiVO₄ Quaternary Oxides as Visible Light Absorbers for Solar Fuel Applications.

Anna Loiudice1,2, Jie Ma1,2, Walter S Drisdell1,2, Tracy M Mattox3, Jason K Cooper1,2, Timothy Thao1, Cinzia Giannini4, Junko Yano1,2, Lin-Wang Wang1,2, Ian D Sharp1,5, Raffaella Buonsanti1,2.   

Abstract

The challenge of fine compositional tuning and microstructure control in complex oxides is overcome by developing a general two-step synthetic approach. Antimony-alloyed bismuth vanadate, which is identified as a novel light absorber for solar fuel applications, is prepared in a wide compositional range. The bandgap of this quaternary oxide linearly decreases with the Sb content, in agreement with first-principles calculations.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  colloidal synthesis; light absorbers; materials discovery; quaternary oxides; solar energy conversion

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Year:  2015        PMID: 26414483     DOI: 10.1002/adma.201502361

Source DB:  PubMed          Journal:  Adv Mater        ISSN: 0935-9648            Impact factor:   30.849


  2 in total

1.  Chemical transformations at the nanoscale: nanocrystal-seeded synthesis of β-Cu2V2O7 with enhanced photoconversion efficiencies.

Authors:  Chethana Gadiyar; Michal Strach; Pascal Schouwink; Anna Loiudice; Raffaella Buonsanti
Journal:  Chem Sci       Date:  2018-05-29       Impact factor: 9.825

2.  Doping-free bandgap tunability in Fe2O3 nanostructured films.

Authors:  Sujit A Kadam; Giang Thi Phan; Duy Van Pham; Ranjit A Patil; Chien-Chih Lai; Yan-Ruei Chen; Yung Liou; Yuan-Ron Ma
Journal:  Nanoscale Adv       Date:  2021-07-29
  2 in total

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