Tetrabromobisphenol A and heavy metal exposure via dust ingestion in an e-waste recycling region in Southeast China.

This study was designed to investigate a prevalent brominated flame retardant tetrabromobisphenol A (TBBPA) and four heavy metals of Pb, Cr, As, Cd in dust samples (52 indoor and 52 outdoor) collected from residential houses in an e-waste recycling area in Southeast China. For TBBPA, the mean concentration in indoor dust (3435 ng/g, dw) was higher than that in outdoor dust (1998 ng/g, dw). For heavy metals, the mean concentrations of Pb, Cr, As, Cd were 399, 151, 48.13, and 5.85 mg/kg in indoor dust, respectively, and were 328, 191, 17.59, and 4.07 mg/kg in outdoor dust, respectively. Except for As, concentrations of TBBPA and other metals decreased with the increased distance away from the e-waste recycling center, suggesting significant contribution of e-waste activities. The daily exposure doses of TBBPA ranged from 0.04 to 7.50 ng/kg-bw/day for adults and from 0.31 to 58.54 ng/kg-bw/day for children, representing the highest values reported to date for TBBPA exposure via dust ingestion. Daily exposure doses of Cr, As, and Cd were all below the reference doses. However, daily exposure dose of Pb for children in areas near the e-waste processing center was above the reference dose, posing significant health concern for children in that region.