| Literature DB >> 26406453 |
Agnieszka Kubiak1, Robert Kołodziuk1, Stanisław Porwański1, Anna Zawisza2.
Abstract
Arylation of 6-O-tert-butyldiphenylsilyl-3,4-di-O-isobutyloxycarbonyl-d-glucal (3) with various phenols in the presence of a catalytic amount of palladium(0) gave the corresponding 2,3- and 3,4-unsaturated β-O-glycosides. The reaction is stereospecific, in all cases, only the β-anomer is formed.Entities:
Keywords: Allylic alkylation reaction; Ferrier rearrangement; Homogeneous catalysis; O-Glycosides; Palladium; d-Glucal
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Year: 2015 PMID： 26406453 DOI： 10.1016/j.carres.2015.08.016
Source DB: PubMed Journal: Carbohydr Res ISSN： 0008-6215 Impact factor: 2.104