| Literature DB >> 26401829 |
Zhenxing Liu1, Haocheng Tan1, Tianren Fu1, Ying Xia1, Di Qiu1, Yan Zhang1, Jianbo Wang1.
Abstract
The first Pd(0)-catalyzed carbene insertion into Si-Si and Sn-Sn bonds has been realized by using N-tosylhydrazones as the carbene precursors. Geminal bis(silane) and geminal bis(stannane) derivatives were obtained in good to excellent yields under mild conditions. Migratory insertion of Pd carbene is supposed to be the key step for the reaction.Entities:
Year: 2015 PMID： 26401829 DOI： 10.1021/jacs.5b09135
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419