| Literature DB >> 26387513 |
Ge Zhang1, Tao Xiong1, Zining Wang1, Guoxing Xu1, Xuedan Wang1, Qian Zhang2.
Abstract
The first controllable, regioselective radical amination of allenes with N-fluoroarylsulfonimide is described to proceed under very mild reaction conditions. With this methodology, a general and straightforward route for the synthesis of both allenamides and fluorinated tetrasubstituted alkenes was realized from a wide range of terminal and internal allenes.Entities:
Keywords: allenes; copper; fluorine; radicals; transition metals
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Year: 2015 PMID： 26387513 DOI： 10.1002/anie.201506066
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336