| Literature DB >> 26332954 |
Yang Ye1, Timothy R Cook2, Shu-Ping Wang1, Jing Wu1, Shijun Li1, Peter J Stang3.
Abstract
We present the formation of a series of chiral metallacycles and metallacages by the use of a BINOL-derived dicarboxylate as a donor that is capable of affording a variety of coordination angles between its two Lewis basic sites. Two squares, two rhomboids, two tetragonal prisms, and one hexagonal prism were successfully formed when the chiral dicarboxylate donor self-assembled with one of four ditopic Pt(II) complexes, including two bimetallic 180° Pt-based acceptors, a 120° bimetallic Pt-based acceptor, and a 90° mononuclear Pt-based acceptor. Their structures were well characterized by (31)P{(1)H} NMR, ESI-MS, CD, and optical rotation analyses.Entities:
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Year: 2015 PMID： 26332954 DOI： 10.1021/jacs.5b07529
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419