Literature DB >> 26331196

Ligandless Regioselective Hydrosilylation of Allenes Catalyzed by Gold Nanoparticles.

Marios Kidonakis1, Manolis Stratakis1.   

Abstract

The first example of Au-catalyzed hydrosilylation of allenes is presented using recyclable gold nanoparticles as catalyst, without the requirement of any external ligands or additives. The hydrosilane addition takes place on the more substituted double bond of terminal allenes in a highly regioselective manner. The observed regioselectivity/reactivity modes are attributed to steric and electronic factors.

Entities:  

Year:  2015        PMID： 26331196     DOI： 10.1021/acs.orglett.5b02236

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes.

Authors:  Chao Wang; Wei Jie Teo; Shaozhong Ge
Journal:  Nat Commun       Date:  2017-12-22       Impact factor: 14.919

2.  Copper-catalyzed regio- and stereo-selective hydrosilylation of terminal allenes to access (E)-allylsilanes.

Authors:  Shaowei Chen; Xiaoqian He; Yi Jin; Yu Lan; Xiao Shen
Journal:  Nat Commun       Date:  2022-06-27       Impact factor: 17.694

Review 3.  Recent Advances in Catalytic Hydrosilylations: Developments beyond Traditional Platinum Catalysts.

Authors:  Leandro Duarte de Almeida; Hongli Wang; Kathrin Junge; Xinjiang Cui; Matthias Beller
Journal:  Angew Chem Int Ed Engl       Date:  2020-12-01       Impact factor: 16.823
  3 in total

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