Literature DB >> 26299566

Formation of α-[KSiH3] by hydrogenolysis of potassium triphenylsilyl.

V Leich1, T P Spaniol, J Okuda.   

Abstract

Hydrogenation of easily accessible potassium triphenylsilyl [K(Me6TREN)SiPh3] gave the hydrogen storage material α-[KSiH3] in high yields by an unusual hydrogenolytic cleavage of silicon-phenyl bonds.

Entities:  

Year:  2015        PMID: 26299566     DOI: 10.1039/c5cc06187c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Alkali Metal Triphenyl- and Trihydridosilanides Stabilized by a Macrocyclic Polyamine Ligand.

Authors:  Danny Schuhknecht; Valeri Leich; Thomas P Spaniol; Iskander Douair; Laurent Maron; Jun Okuda
Journal:  Chemistry       Date:  2020-02-18       Impact factor: 5.236

  1 in total

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