| Literature DB >> 26298108 |
Nathaniel S Barlow1, Andrew J Schultz2, Steven J Weinstein3, David A Kofke2.
Abstract
The mathematical structure imposed by the thermodynamic critical point motivates an approximant that synthesizes two theoretically sound equations of state: the parametric and the virial. The former is constructed to describe the critical region, incorporating all scaling laws; the latter is an expansion about zero density, developed from molecular considerations. The approximant is shown to yield an equation of state capable of accurately describing properties over a large portion of the thermodynamic parameter space, far greater than that covered by each treatment alone.Year: 2015 PMID: 26298108 DOI: 10.1063/1.4929392
Source DB: PubMed Journal: J Chem Phys ISSN: 0021-9606 Impact factor: 3.488