Fingers Crossed: Optical Activity of a Chiral Dimer of Plasmonic Nanorods.

We investigate theoretically the optical activity of a dimer of plasmonic nanoantennas, mimicking the geometry of a molecule with two isolated chromophores, a situation commonly described as exciton coupling in organic chemistry. As the scale of the system increases and approaches the wavelength of visible light, a rich variety of effects arise that are unique to the plasmonic case. Scattering of light by the particles, negligible in very small clusters, strongly perturbs, and eventually dominates, the optical activity. Additionally, retardation effects in dimers with an interparticle separation commensurate with the wavelength of the incident light affect the electromagnetic coupling between the particles and lead to an asymmetric circular dichroism spectrum. We identify conditions for efficient interaction and predict remarkably large anisotropy factors.