Literature DB >> 26293313

Uncovering the Role of Metal Catalysis in Tetrazole Formation by an In Situ Cycloaddition Reaction: An Experimental Approach.

Di-Chang Zhong1, Ya-Qiong Wen2, Ji-Hua Deng2, Xu-Zhong Luo3, Yun-Nan Gong2, Tong-Bu Lu4.   

Abstract

Using an experimental approach, the role of metal catalysis has been investigated in the in situ cycloaddition reaction of nitrile with azide to form tetrazoles. It has been shown that metal catalysis serves to activate the cyano group in the nitrile reagent by a coordinative interaction.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  cycloaddition; metal catalysis; reaction mechanisms; structure elucidation; tetrazoles

Year:  2015        PMID： 26293313     DOI： 10.1002/anie.201505118

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  3 in total

1.  PbII-catalyzed transformation of aromatic nitriles to heptanitrogen anions via sodium azide: a combined experimental and theoretical study.

Authors:  Rong-Yi Huang; Chao Zhang; Da Yan; Zhi Xiong; Heng Xu; Xiao-Ming Ren
Journal:  RSC Adv       Date:  2018-11-29       Impact factor: 4.036

2.  An intramolecular relay catalysis strategy for Knoevenagel condensation and 1,3-dipolar cycloaddition domino reactions.

Authors:  Xiaofeng Yuan; Zijuan Wang; Qiang Zhang; Jun Luo
Journal:  RSC Adv       Date:  2019-07-30       Impact factor: 3.361

3.  Crystal Engineering and Photomagnetic Studies of CN-Bridged Coordination Polymers Based on Octacyanidometallates(IV) and [Ni(cyclam)]2.

Authors:  Michał Heczko; Ewa Sumińska; Dawid Pinkowicz; Beata Nowicka
Journal:  Inorg Chem       Date:  2022-08-23       Impact factor: 5.436
  3 in total

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