| Literature DB >> 26289229 |
K Starkl Renar1, S Pečar, J Iskra.
Abstract
Cyclic and acyclic ketones were selectively converted to gem-dihydroperoxides in 72-99% yield with 30% aq. hydrogen peroxide by azeotropic distillation of water from the reaction mixture without any catalyst. The reactions were more selective than with 100% H2O2 and due to neutral conditions also less stable products could be obtained.Entities:
Mesh：
Substances：
Year: 2015 PMID： 26289229 DOI： 10.1039/c5ob01503k
Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876