| Literature DB >> 26288856 |
Sabrina I Kalläne1, Thomas Braun, Michael Teltewskoi, Beatrice Braun, Roy Herrmann, Reik Laubenstein.
Abstract
The activation of CO2, CS2 as well as of PhNCO at [Rh(Bpin)(PEt3)3] led to C=X bond cleavage and the formation of {RhXBpin} species (X = O, S, N). Treatment of the boryl complex [Rh(Bpin)(PEt3)3] with 0.5 equivalents of CS2 resulted in the fragmentation of CS2 and the formation of the remarkable μ-carbido complex trans-[Rh2(μ-C)(SBpin)2(PEt3)4].Entities:
Year: 2015 PMID： 26288856 DOI： 10.1039/c5cc05606c
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222