Literature DB >> 26278887

Magnesium-catalysed hydroboration of isonitriles.

Catherine Weetman1, Michael S Hill, Mary F Mahon.   

Abstract

A β-diketiminato magnesium alkyl complex is shown to be an effective pre-catalyst for the first reported catalytic hydroboration of organic isonitriles, RNC, with HBpin. The reaction proceeds under mild conditions when R = alkyl and provides access to the corresponding 1,2-diborylated amine products.

Entities:  

Year:  2015        PMID: 26278887     DOI: 10.1039/c5cc05708f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  6 in total

Review 1.  s-Block Metal Catalysts for the Hydroboration of Unsaturated Bonds.

Authors:  Marc Magre; Marcin Szewczyk; Magnus Rueping
Journal:  Chem Rev       Date:  2022-03-07       Impact factor: 72.087

2.  Pincer-Supported Gallium Complexes for the Catalytic Hydroboration of Aldehydes, Ketones and Carbon Dioxide.

Authors:  Lingyu Liu; Siu-Kwan Lo; Cory Smith; Jose M Goicoechea
Journal:  Chemistry       Date:  2021-10-27       Impact factor: 5.020

3.  1-Alkali-metal-2-alkyl-1,2-dihydropyridines: Soluble Hydride Surrogates for Catalytic Dehydrogenative Coupling and Hydroboration Applications.

Authors:  Ross McLellan; Alan R Kennedy; Robert E Mulvey; Samantha A Orr; Stuart D Robertson
Journal:  Chemistry       Date:  2017-11-03       Impact factor: 5.236

4.  Organoaluminum Compounds as Catalysts for Monohydroboration of Carbodiimides.

Authors:  Qiumiao Shen; Xiaoli Ma; Wenling Li; Wenqing Liu; Yi Ding; Zhi Yang; Herbert W Roesky
Journal:  Chemistry       Date:  2019-08-13       Impact factor: 5.236

5.  Magnesium-catalysed nitrile hydroboration.

Authors:  Catherine Weetman; Mathew D Anker; Merle Arrowsmith; Michael S Hill; Gabriele Kociok-Köhn; David J Liptrot; Mary F Mahon
Journal:  Chem Sci       Date:  2015-10-20       Impact factor: 9.825

6.  Donor-influenced Structure-Activity Correlations in Stoichiometric and Catalytic Reactions of Lithium Monoamido-Monohydrido-Dialkylaluminates.

Authors:  Lara E Lemmerz; Ross McLellan; Neil R Judge; Alan R Kennedy; Samantha A Orr; Marina Uzelac; Eva Hevia; Stuart D Robertson; Jun Okuda; Robert E Mulvey
Journal:  Chemistry       Date:  2018-06-13       Impact factor: 5.236

  6 in total

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