Literature DB >> 26261944

Direct Observation of Ground-State Product Formation in a 1,3-Cyclohexadiene Ring-Opening Reaction.

Shunsuke Adachi1,2, Motoki Sato1, Toshinori Suzuki1,2.   

Abstract

Ultrafast photoelectron imaging using a 90 nm vacuum-UV probe pulse is applied to the ring-opening reaction of 1,3-cyclohexadiene (CHD) in the gas phase, and formation of 1,3,5-hexatriene (HT) and CHD in their electronic ground states is observed in real time. The analysis of the transient photoelectron kinetic energy spectra reveals the branching ratio into HT and CHD as 3:7 upon 270 nm photoexcitation. The ratio is in reasonable agreement with the experimental values reported for the liquid phase and theoretical values for the gas phase, resolving the discrepancy.

Entities:  

Keywords:  1,3,5-hexatriene; conical intersection; imaging; photoelectron spectroscopy; reaction dynamics

Mesh：

Substances：

Year:  2015        PMID： 26261944     DOI： 10.1021/jz502487r

Source DB:  PubMed          Journal:  J Phys Chem Lett        ISSN： 1948-7185            Impact factor:   6.475


  5 in total

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Authors:  Mizuho Fushitani; Akiyoshi Hishikawa
Journal:  Struct Dyn       Date:  2016-10-14       Impact factor: 2.920

2.  Acetylacetone photodynamics at a seeded free-electron laser.

Authors:  R J Squibb; M Sapunar; A Ponzi; R Richter; A Kivimäki; O Plekan; P Finetti; N Sisourat; V Zhaunerchyk; T Marchenko; L Journel; R Guillemin; R Cucini; M Coreno; C Grazioli; M Di Fraia; C Callegari; K C Prince; P Decleva; M Simon; J H D Eland; N Došlić; R Feifel; M N Piancastelli
Journal:  Nat Commun       Date:  2018-01-04       Impact factor: 14.919

3.  Observation of the molecular response to light upon photoexcitation.

Authors:  Haiwang Yong; Nikola Zotev; Jennifer M Ruddock; Brian Stankus; Mats Simmermacher; Andrés Moreno Carrascosa; Wenpeng Du; Nathan Goff; Yu Chang; Darren Bellshaw; Mengning Liang; Sergio Carbajo; Jason E Koglin; Joseph S Robinson; Sébastien Boutet; Michael P Minitti; Adam Kirrander; Peter M Weber
Journal:  Nat Commun       Date:  2020-05-01       Impact factor: 14.919

4.  Signatures of Conical Intersection Dynamics in the Time-Resolved Photoelectron Spectrum of Furan: Theoretical Modeling with an Ensemble Density Functional Theory Method.

Authors:  Michael Filatov; Seunghoon Lee; Hiroya Nakata; Cheol-Ho Choi
Journal:  Int J Mol Sci       Date:  2021-04-20       Impact factor: 5.923

5.  Restriction of the conrotatory motion in photo-induced 6π electrocyclic reaction: formation of the excited state of the closed-ring isomer in the cyclization.

Authors:  Tatsuhiro Nagasaka; Hikaru Sotome; Soichiro Morikawa; Lucas Martinez Uriarte; Michel Sliwa; Tsuyoshi Kawai; Hiroshi Miyasaka
Journal:  RSC Adv       Date:  2020-05-27       Impact factor: 3.361
  5 in total

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