Formal Gold-to-Gold Transmetalation of an Alkynyl Group Mediated by Palladium: A Bisalkynyl Gold Complex as a Ligand to Palladium.

The reaction of [Au(C≡C-n-Bu)]n with [Pd(η(3) -allyl)Cl(PPh3 )] results in a ligand and alkynyl rearrangement, and leads to the heterometallic complex [Pd(η(3) -allyl){Au(C≡C-n-Bu)2 }]2 (3) with an unprecedented bridging bisalkynyl-gold ligand coordinated to palladium. This is a formal gold-to-gold transmetalation that occurs through reversible alkynyl transmetalations between gold and palladium.