Literature DB >> 26248643

A Gallium-Substituted Distibene and an Antimony-Analogue Bicyclo[1.1.0]butane: Synthesis and Solid-State Structures.

Lars Tuscher1, Chelladurai Ganesamoorthy1, Dieter Bläser1, Christoph Wölper1, Stephan Schulz2.   

Abstract

RGa {R=HC[C(Me)N(2,6-iPr2C6H3)]2} reacts with Sb(NMe2)3 with insertion into the Sb-N bond and elimination of RGa(NMe2)2 (2), yielding the Ga-substituted distibene R(Me2N)GaSb=SbGa(NMe2 )R (1). Thermolysis of 1 proceeded with elimination of RGa and 2 and subsequent formation of the bicyclo[1.1.0]butane analogue [R(Me2N)Ga]2Sb4 (3).
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  Group 13 elements; main-group elements; metal-metal interactions; multiple bonding

Year:  2015        PMID： 26248643     DOI： 10.1002/anie.201502827

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  5 in total

1.  From stable Sb- and Bi-centered radicals to a compound with a Ga=Sb double bond.

Authors:  Chelladurai Ganesamoorthy; Christoph Helling; Christoph Wölper; Walter Frank; Eckhard Bill; George E Cutsail; Stephan Schulz
Journal:  Nat Commun       Date:  2018-01-08       Impact factor: 14.919

2.  Synthesis of distibiranes and azadistibiranes by cycloaddition reactions of distibenes with diazomethanes and azides.

Authors:  Hanns M Weinert; Christoph Wölper; Stephan Schulz
Journal:  Chem Sci       Date:  2022-03-03       Impact factor: 9.825

3.  Bis-Phosphaketenes LM(PCO)2 (M=Ga, In): A New Class of Reactive Group 13 Metal-Phosphorus Compounds.

Authors:  Mahendra K Sharma; Pratima Dhawan; Christoph Helling; Christoph Wölper; Stephan Schulz
Journal:  Chemistry       Date:  2022-03-14       Impact factor: 5.020

4.  Peptide Backbone Directed Self-Assembly of Merocyanine Oligomers into Duplex Structures.

Authors:  Bin Liu; Yvonne Vonhausen; Alexander Schulz; Claudia Höbartner; Frank Würthner
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-23       Impact factor: 16.823

5.  Transfer of polyantimony units.

Authors:  Veronika Heinl; Andreas E Seitz; Gábor Balázs; Michael Seidl; Manfred Scheer
Journal:  Chem Sci       Date:  2021-06-17       Impact factor: 9.825
  5 in total

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