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Literature DB >> 26246464

Formation and characterization of the boron dicarbonyl complex [B(CO)2](-).

Qingnan Zhang¹, Wan-Lu Li², Cong-Qiao Xu², Mohua Chen¹, Mingfei Zhou³, Jun Li⁴, Diego M Andrada⁵, Gernot Frenking^6,7.

Abstract

We report the synthesis and spectroscopic characterization of the boron dicarbonyl complex [B(CO)2 ](-) . The bonding situation is analyzed and compared with the aluminum homologue [Al(CO)2 ](-) using state-of-the-art quantum chemical methods.

Entities: Chemical Gene

Keywords: bonding analysis; boron dicarbonyl compound; matrix isolation; quantum chemical calculations

Year: 2015 PMID： 26246464 DOI： 10.1002/anie.201503686

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

12 in total

1. Stability and donor-acceptor bond in dinuclear organometallics CpM₁-M₂Cl₃ (M₁, M₂ = B, Al, Ga, In; Cp = η ⁵-C₅H₅).

Authors: Yaru Dang; Lingpeng Meng; Mei Qin; Qingzhong Li; Xiaoyan Li
Journal: J Mol Model Date: 2017-12-07 Impact factor: 1.810

2. Neutral zero-valent s-block complexes with strong multiple bonding.

Authors: Merle Arrowsmith; Holger Braunschweig; Mehmet Ali Celik; Theresa Dellermann; Rian D Dewhurst; William C Ewing; Kai Hammond; Thomas Kramer; Ivo Krummenacher; Jan Mies; Krzysztof Radacki; Julia K Schuster
Journal: Nat Chem Date: 2016-06-06 Impact factor: 24.427

3. Energy Decomposition Analysis Coupled with Natural Orbitals for Chemical Valence and Nucleus-Independent Chemical Shift Analysis of Bonding, Stability, and Aromaticity of Functionalized Fulvenes: A Bonding Insight.

Authors: Sai Manoj N V T Gorantla; Kartik Chandra Mondal
Journal: ACS Omega Date: 2021-07-06

Formation and characterization of the boron dicarbonyl complex [B(CO)2](-).

1. Stability and donor-acceptor bond in dinuclear organometallics CpM₁-M₂Cl₃ (M₁, M₂ = B, Al, Ga, In; Cp = η ⁵-C₅H₅).

2. Neutral zero-valent s-block complexes with strong multiple bonding.

3. Energy Decomposition Analysis Coupled with Natural Orbitals for Chemical Valence and Nucleus-Independent Chemical Shift Analysis of Bonding, Stability, and Aromaticity of Functionalized Fulvenes: A Bonding Insight.

4. Chemical Bonding in Homoleptic Carbonyl Cations [M{Fe(CO)₅ }₂ ]⁺ (M=Cu, Ag, Au).

5. The Bonding Situation in Metalated Ylides.

6. Octacarbonyl Ion Complexes of Actinides [An(CO)₈ ]^+/- (An=Th, U) and the Role of f Orbitals in Metal-Ligand Bonding.

7. The Valence Orbitals of the Alkaline-Earth Atoms.

8. Side-On Bonded Beryllium Dinitrogen Complexes.

Review 9. Transition-Metal Chemistry of Alkaline-Earth Elements: The Trisbenzene Complexes M(Bz)₃ (M=Sr, Ba).

10. Stabilization of Linear C₃ by Two Donor Ligands: A Theoretical Study of L-C₃ -L (L=PPh₃ , NHC^Me , cAAC^Me )*.

Review 9. Transition-Metal Chemistry of Alkaline-Earth Elements: The Trisbenzene Complexes M(Bz)3 (M=Sr, Ba).

Review 9. Transition-Metal Chemistry of Alkaline-Earth Elements: The Trisbenzene Complexes M(Bz)₃ (M=Sr, Ba).