| Literature DB >> 26224158 |
A M Träff1, M Janjetovic, G Hilmersson.
Abstract
Aliphatic 1,2-aminofluorides undergo extremely fast substitution reactions under the influence of lanthanum tris(hexamethyldisilazide). The substitution proceeds via an in situ generated aziridinium ion intermediate, which subsequently undergoes ring opening by addition of a nucleophile, yielding various β-substituted amines.Entities:
Year: 2015 PMID： 26224158 DOI： 10.1039/c5cc04723d
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222