Literature DB >> 26221636

Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster.

C Lichtenberg1, L Viciu, M Vogt, R E Rodríguez-Lugo, M Adelhardt, J Sutter, M M Khusniyarov, K Meyer, B de Bruin, E Bill, H Grützmacher.   

Abstract

A low-valent trinuclear iron complex with an unusual linear Fe(I)-Fe(II)-Fe(I) unit is presented. It is accessed in a rational approach using a salt metathesis reaction between a new anionic Fe(I) containing heterocycle and FeCl2. Its electronic structure was studied by single crystal XRD analysis, EPR and Mössbauer spectroscopy, and magnetic susceptibility measurements.

Entities:  

Year:  2015        PMID: 26221636     DOI: 10.1039/c5cc04908c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Cationic Bismuth Aminotroponiminates: Charge Controls Redox Properties.

Authors:  Anna Hanft; Krzysztof Radacki; Crispin Lichtenberg
Journal:  Chemistry       Date:  2021-01-26       Impact factor: 5.236

2.  Ligand- and Metal-Based Reactivity of a Neutral Ruthenium Diolefin Diazadiene Complex: The Innocent, the Guilty and the Suspicious.

Authors:  Vivek Sinha; Bruno Pribanic; Bas de Bruin; Monica Trincado; Hansjörg Grützmacher
Journal:  Chemistry       Date:  2018-02-27       Impact factor: 5.236

  2 in total

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