Literature DB >> 26219388

Ruthenium-catalyzed nucleophilic fluorination of halobenzenes.

Andrey I Konovalov1, Evgeniya O Gorbacheva, Fedor M Miloserdov, Vladimir V Grushin.   

Abstract

The first π-coordination-catalyzed nucleophilic fluorination of unactivated aryl halides has been demonstrated. Chlorobenzene reacts with alkali metal fluorides (CsF, KF) in the presence of a Cp*Ru catalyst at 120-180 °C to give fluorobenzene.

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Year:  2015        PMID： 26219388     DOI： 10.1039/c5cc05436b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Toward Novel [18F]Fluorine-Labeled Radiotracers for the Imaging of α-Synuclein Fibrils.

Authors:  Bright C Uzuegbunam; Junhao Li; Wojciech Paslawski; Wolfgang Weber; Per Svenningsson; Hans Ågren; Behrooz Hooshyar Yousefi
Journal:  Front Aging Neurosci       Date:  2022-04-29       Impact factor: 5.702

2.  Triarylmethane Fluorophores Resistant to Oxidative Photobluing.

Authors:  Alexey N Butkevich; Mariano L Bossi; Gražvydas Lukinavičius; Stefan W Hell
Journal:  J Am Chem Soc       Date:  2019-01-02       Impact factor: 15.419

3.  18F-Deoxyfluorination of Phenols via Ru π-Complexes.

Authors:  M Hassan Beyzavi; Debashis Mandal; Martin G Strebl; Constanze N Neumann; Erica M D'Amato; Junting Chen; Jacob M Hooker; Tobias Ritter
Journal:  ACS Cent Sci       Date:  2017-08-03       Impact factor: 14.553
  3 in total

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