Literature DB >> 26215256

Cluster-π electronic interaction in a superatomic Au13 cluster bearing σ-bonded acetylide ligands.

Mizuho Sugiuchi1, Yukatsu Shichibu, Takayuki Nakanishi, Yasuchika Hasegawa, Katsuaki Konishi.   

Abstract

An organometallic Au13 cluster having two σ-bonded acetylide ligands was synthesized and its structure was determined by X-ray crystallography. Absorption spectral studies indicated the presence of electronic coupling between the superatomic Au13 core and the acetylide π-orbitals, which was supported by theoretical considerations.

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Year:  2015        PMID： 26215256     DOI： 10.1039/c5cc04312c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Hydrogen bonds to Au atoms in coordinated gold clusters.

Authors:  Md Abu Bakar; Mizuho Sugiuchi; Mitsuhiro Iwasaki; Yukatsu Shichibu; Katsuaki Konishi
Journal:  Nat Commun       Date:  2017-09-18       Impact factor: 14.919

2.  Diphosphine-protected ultrasmall gold nanoclusters: opened icosahedral Au13 and heart-shaped Au8 clusters.

Authors:  Shan-Shan Zhang; Lei Feng; Ravithree D Senanayake; Christine M Aikens; Xing-Po Wang; Quan-Qin Zhao; Chen-Ho Tung; Di Sun
Journal:  Chem Sci       Date:  2017-12-04       Impact factor: 9.825

3.  Chiroptical activity of Au13 clusters: experimental and theoretical understanding of the origin of helical charge movements.

Authors:  Yukatsu Shichibu; Yuri Ogawa; Mizuho Sugiuchi; Katsuaki Konishi
Journal:  Nanoscale Adv       Date:  2020-11-05
  3 in total

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