Literature DB >> 26212946

Generation of chlorine by-products in simulated wash water.

Cangliang Shen1, Pauline Norris2, Olivia Williams3, Stephanie Hagan4, KaWang Li5.   

Abstract

Free chlorine (FC) reacting with organic matter in wash water promotes the formation of chlorine by-products. This study aims to evaluate the dynamic impact of FC and organic load on the generation of haloacetic acids (HAAs) and trihalomethanes (THMs) in simulated wash water. Lettuce juice was sequentially added into FC solution with FC periodically replenished. Water samples were collected after each lettuce juice addition to measure water qualities and determine HAAs and THMs using US-Environmental-Protection-Agency (EPA) methods. Concentrations of 88-2103 μg/l of total HAAs and 20.79-859.47 μg/l of total THMs were detected during the study. Monobromoacetic, tribromoacetic, chlorodibromoacetic and trichloroacetic acid were the major HAAs components. Chloroform (trichloromethane) was the primary THMs present. A significant correlation of HAAs with chemical oxygen demand and THMs with FC was observed. Results indicated that optimizing wash water sanitizing systems to limit organic matters and maintain minimal effective FC concentration is critical.
Copyright © 2015 Elsevier Ltd. All rights reserved.

Entities:  

Keywords:  Bromodichloromethane (PubChem CID: 6359); Chlorodibromoacetic acid (PubChem CID: 115266); Dibromochloromethane (PubChem CID: 31296); Free chlorine; Haloacetic acids; Monobromoacetic acid (PubChem CID: 6227); Organic loads; Tribromoacetic acid (PubChem CID: 6415); Tribromomethane (PubChem CID: 5558); Trichloroacetic acid (PubChem CID: 6421); Trichloromethane (PubChem CID: 6212); Trihalomethanes

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Year:  2015        PMID: 26212946     DOI: 10.1016/j.foodchem.2015.04.146

Source DB:  PubMed          Journal:  Food Chem        ISSN: 0308-8146            Impact factor:   7.514


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