Literature DB >> 26211412

Redox-Active NO(x) Ligands in Palladium-Mediated Processes.

Ian J S Fairlamb1.   

Abstract

This Minireview highlights the redox and non-innocent behavior of NO(x) ligands (x=1, 2, or 3) in selected Pd-mediated processes, for example, alkene and aromatic oxidation processes. A focus is placed on mechanistic understanding and linking recent transformations, such as C-H bond activation/functionalization and Wacker oxidation, with previous work on the functionalization of aromatics and alkenes by Pd(II) salts.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  CC coupling; oxidation; palladium; reaction mechanisms; redox reactions

Year:  2015        PMID： 26211412     DOI： 10.1002/anie.201411487

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

1.  Palladium-Catalyzed Aerobic Intramolecular Aminoacetoxylation of Alkenes Enabled by Catalytic Nitrate.

Authors:  Jiaming Li; Robert H Grubbs; Brian M Stoltz
Journal:  Org Lett       Date:  2016-10-18       Impact factor: 6.005

2.  Direct Access to β-Fluorinated Aldehydes by Nitrite-Modified Wacker Oxidation.

Authors:  Crystal K Chu; Daniel T Ziegler; Brian Carr; Zachary K Wickens; Robert H Grubbs
Journal:  Angew Chem Int Ed Engl       Date:  2016-05-25       Impact factor: 15.336

3.  Palladium(II)-Catalysed Aminocarbonylation of Terminal Alkynes for the Synthesis of 2-Ynamides: Addressing the Challenges of Solvents and Gas Mixtures.

Authors:  N Louise Hughes; Clare L Brown; Andrew A Irwin; Qun Cao; Mark J Muldoon
Journal:  ChemSusChem       Date:  2017-01-23       Impact factor: 8.928

4.  Strong Exchange Coupling in a Trimetallic Radical-Bridged Cobalt(II)-Hexaazatrinaphthylene Complex.

Authors:  Jani O Moilanen; Nicholas F Chilton; Benjamin M Day; Thomas Pugh; Richard A Layfield
Journal:  Angew Chem Int Ed Engl       Date:  2016-03-21       Impact factor: 15.336
  4 in total

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