Literature DB >> 26207327

Enhancement of 4-electron O2 reduction by a Cu(ii)-pyridylamine complex via protonation of a pendant pyridine in the second coordination sphere in water.

Hiroaki Kotani1, Tomomi Yagi, Tomoya Ishizuka, Takahiko Kojima.   

Abstract

We have synthesised a novel copper(ii) complex with a pyridine pendant as a proton relay port for electrocatalytic 4e(-) reduction of O2 in water. The enhancement of the electrocatalytic O2 reduction via protonation of the pyridine pendant is demonstrated in comparison with a copper(ii) complex without the pyridine pendant.

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Year:  2015        PMID： 26207327     DOI： 10.1039/c5cc03012a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Interactions of Metal-Based and Ligand-Based Electronic Spins in Neutral Tripyrrindione π Dimers.

Authors:  Ritika Gautam; Andrei V Astashkin; Tsuhen M Chang; Jason Shearer; Elisa Tomat
Journal:  Inorg Chem       Date:  2017-05-12       Impact factor: 5.165

2.  Ligand Identity-Induced Generation of Enhanced Oxidative Hydrogen Atom Transfer Reactivity for a CuII2(O2•-) Complex Driven by Formation of a CuII2(-OOH) Compound with a Strong O-H Bond.

Authors:  David A Quist; Melanie A Ehudin; Andrew W Schaefer; Gregory L Schneider; Edward I Solomon; Kenneth D Karlin
Journal:  J Am Chem Soc       Date:  2019-07-30       Impact factor: 15.419
  2 in total

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