Literature DB >> 26201084

Exploration of Dimethylzinc-Mediated Radical Reactions.

Ken-Ichi Yamada1, Kiyoshi Tomioka2.   

Abstract

In this account, our studies on radical reactions that are promoted by dimethylzinc and air are described. Advantages of this reagent and differences from conventional radical initiators, such as triethylborane, are discussed.
Copyright © 2015 The Chemical Society of Japan and Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  C(sp3)-H bond functionalization; carbon-carbon bond formation; dimethylzinc; radical reactions; umpolung

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Year:  2015        PMID： 26201084     DOI： 10.1002/tcr.201500017

Source DB:  PubMed          Journal:  Chem Rec        ISSN： 1528-0691            Impact factor:   6.771


  2 in total

1.  Synthesis of amino-diamondoid pharmacophores via photocatalytic C-H aminoalkylation.

Authors:  William K Weigel; Hoang T Dang; Hai-Bin Yang; David B C Martin
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2.  1,2-Addition of Diethylzinc to a Bis(Imidazolyl)ketone Ligand.

Authors:  Emma Folkertsma; Sanne H Benthem; Johann T B H Jastrzebski; Martin Lutz; Marc-Etienne Moret; Robertus J M Klein Gebbink
Journal:  Eur J Inorg Chem       Date:  2018-02-12       Impact factor: 2.524
  2 in total

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