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Literature DB >> 26196854

A Molecular Diode with a Statistically Robust Rectification Ratio of Three Orders of Magnitude.

Li Yuan¹, Rochus Breuer², Li Jiang¹, Michael Schmittel², Christian A Nijhuis^1,3.

Abstract

This paper describes a molecular diode with high, statistically robust, rectification ratios R of 1.1 × 10(3). These diodes operate with a new mechanism of charge transport based on sequential tunneling involving both the HOMO and HOMO-1 positioned asymmetrically inside the junction. In addition, the diodes are stable and withstand voltage cycling for 1500 times, and the yield in working junctions is 90%.

Keywords: Molecular diode; molecular orbitals; rectification ratio; tunnelling junctions

Year: 2015 PMID： 26196854 DOI： 10.1021/acs.nanolett.5b02014

Source DB: PubMed Journal: Nano Lett ISSN： 1530-6984 Impact factor: 11.189

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Cited

20 in total

1. Molecular diodes with rectification ratios exceeding 10⁵ driven by electrostatic interactions.

Authors: Xiaoping Chen; Max Roemer; Li Yuan; Wei Du; Damien Thompson; Enrique Del Barco; Christian A Nijhuis
Journal: Nat Nanotechnol Date: 2017-07-03 Impact factor: 39.213

Review 2. Rotaxane nanomachines in future molecular electronics.

Authors: Peiqiao Wu; Bhushan Dharmadhikari; Prabir Patra; Xingguo Xiong
Journal: Nanoscale Adv Date: 2022-06-24

3. Mixed Monolayers of Spiropyrans Maximize Tunneling Conductance Switching by Photoisomerization at the Molecule-Electrode Interface in EGaIn Junctions.

Authors: Sumit Kumar; Jochem T van Herpt; Régis Y N Gengler; Ben L Feringa; Petra Rudolf; Ryan C Chiechi
Journal: J Am Chem Soc Date: 2016-09-16 Impact factor: 15.419

4. Fluorinated benzalkylsilane molecular rectifiers.

Authors: Zachary A Lamport; Angela D Broadnax; David Harrison; Katrina J Barth; Lee Mendenhall; Clayton T Hamilton; Martin Guthold; Timo Thonhauser; Mark E Welker; Oana D Jurchescu
Journal: Sci Rep Date: 2016-11-29 Impact factor: 4.379

Review 5. Molecular Diode Studies Based on a Highly Sensitive Molecular Measurement Technique.

Authors: Madoka Iwane; Shintaro Fujii; Manabu Kiguchi
Journal: Sensors (Basel) Date: 2017-04-26 Impact factor: 3.576

6. A Single-Level Tunnel Model to Account for Electrical Transport through Single Molecule- and Self-Assembled Monolayer-based Junctions.

Authors: Alvar R Garrigues; Li Yuan; Lejia Wang; Eduardo R Mucciolo; Damien Thompon; Enrique Del Barco; Christian A Nijhuis
Journal: Sci Rep Date: 2016-05-24 Impact factor: 4.379

A Molecular Diode with a Statistically Robust Rectification Ratio of Three Orders of Magnitude.

1. Molecular diodes with rectification ratios exceeding 10⁵ driven by electrostatic interactions.

Review 2. Rotaxane nanomachines in future molecular electronics.

3. Mixed Monolayers of Spiropyrans Maximize Tunneling Conductance Switching by Photoisomerization at the Molecule-Electrode Interface in EGaIn Junctions.

4. Fluorinated benzalkylsilane molecular rectifiers.

Review 5. Molecular Diode Studies Based on a Highly Sensitive Molecular Measurement Technique.

6. A Single-Level Tunnel Model to Account for Electrical Transport through Single Molecule- and Self-Assembled Monolayer-based Junctions.

7. Electrostatic control over temperature-dependent tunnelling across a single-molecule junction.

8. Chemical control over the energy-level alignment in a two-terminal junction.

9. A 17 GHz molecular rectifier.

10. Mechanically and Electrically Robust Self-Assembled Monolayers for Large-Area Tunneling Junctions.