Tuning of giant 2D-chiroptical response using achiral metasurface integrated with graphene.

Tuning the chiroptical response of a molecule is crucial for detecting the material's chirality. Here, we demonstrate a pronounced circular conversion dichroism (CCD) by using an achiral metasurface (AMS) which is composed of a rectangular reflectarray of Au squares separated from a continuous Au film by a dielectric interlayer. This extrinsically 2D chirality originates from the mutual orientation between the AMS and oblique incident wave. The AMS is further incorporated with graphene to tune the CCD spectra in the mid-infrared (MIR) region by electrically modulating the graphene's Fermi level. This approach offers a high fabrication tolerance and will be a promising candidate for controlling electromagnetic (EM) waves in the MIR region from 1500 to 3000 nm.