| Literature DB >> 26186178 |
Xinyao Li1, Xinwei Li1, Ning Jiao1,2.
Abstract
A novel and efficient Rh-catalyzed carbonylation and annulation of simple anilines with CO and alkynes through N-H and C-H bond activation for the direct synthesis of quinolin-2(1H)-ones has been developed. Simple anilines without preactivation, broad substrate scope with hetero/polycycles, and high-value products make this protocol very practical and attractive. A key rhodacycle complex was isolated and well-characterized.Entities:
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Year: 2015 PMID： 26186178 DOI： 10.1021/jacs.5b05843
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419